Steam
Water can exist
in the form of solid, liquid and gas as ice, water and steam respectively. If
heat energy is added to water, its temperature rises until a value is reached
at which the water can no longer exit as a liquid. We call this the "saturation"
point and with any further addition of energy, some of the water will boil
off as steam. This evaporation requires relatively large amounts of energy, and
while it is being added, the water and the steam released are both at the same
temperature. Equally, if we can encourage the steam to release the energy that
was added to evaporate it, then the steam will condense and water at the same
temperature will be formed.
Why
use Steam?
Steam
is produced by evaporation of water, which is a relatively cheap and plentiful
commodity in most parts of the world. Its temperature can be adjusted very accurately
by the control of its pressure, using simple valves; it carries relatively large
amounts of energy in a small mass, and when it is encouraged to condensate back
to water, high rates of energy flow (into the material being heated) are obtained,
so that the heat using plant does not have to be unduly large.
Thus
steam is most economical,flexible and versatile tool for industry wherever heating
is required.
Liquid
Enthalpy
Liquid
enthalpy is the "Enthalpy" (heat energy) in the water when it has been
raised to its boiling point to produce steam, and is measured in kJ/kg, its symbol
is hf. (once known as "Sensible Heat")
Enthalpy
of Evaporation (the heat content of steam)
The
Enthalpy of evaporation is the heat energy to be added to the water (when it has
been raised to its boiling point) in order to change it into steam. There is no
change in temperature, the steam produced is at the same temperature as the water
from which it is produced, but the heat energy added to the water changes its
state from water into steam at the same temperature.
When
the steam condenses back into water, it gives up its enthalpy of evaporation,
which it had acquired on changing from water to steam. The enthalpy of evaporation
is measured in kJ/kg its symbol is hfg. Enthalpy of evaporation is
also known as latent heat.
The
temperature at which water boils increases as the pressure increases. From this
it is evident that as the steam pressure increases, the
usable heat energy in the steam (enthalpy of evaporation) which is given up when
the steam condenses, actually decreases.
The
sum of the two enthalpies is known as the enthalpy of saturated steam. This enthalpy
is the total heat energy, which is stored in the steam.
| Pressure(Bar)
| Temperature
oC |
Enthalpy
in kJ/kg |
Volume
(m3/kg) |
|
Water
(hf) |
Evaporation
(hfg) |
Steam(hg)
|
| 0
| 100
| 419
| 2257
| 2676
| 1.673
|
| 1
| 120
| 506
| 2201
| 2707
| 0.881
|
| 2
| 134
| 562
| 2163
| 2725
| 0.603
|
| 3
| 144
| 605
| 2133
| 2738
| 0.461
|
| 4
| 152
| 671
| 2108
| 2749
| 0.374
|
| 5
| 159
| 641
| 2086
| 2757
| 0.315
|
| 6
| 165
| 697
| 2066
| 2763
| 0.272
|
| 7
| 170
| 721
| 2048
| 2769
| 0.240
|
Table:
Extract from the steam tables
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